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Polystannanes have also been synthesized using the Wurtz synthetic route with dibutyldichlorotin(IV) with a 15-crown-5-sodium catalyzed reaction (82). An improved Wurtz synthesis by Devylder and coworkers (83) has provided polystannanes with M N 106 as estimated by gel permeation chromatography. Although comparing a polystannane with polystyrene does not lead to good precision in molecular mass measurements, this recent polystannane is undoubtedly a high polymer. Polycarbosilanes have also been prepared by reductive coupling. Two examples are shown in Figure 2.42. One, in which magnesium metal is used as the reductant, leads to a carbosilane with alternating aromatic carbon rings and silanes with an organic R group and an ethoxo (ethoxy) group with M N 6000 to 18,000 (84). The ethoxo group can be metathetically replaced with uoro, chloro, hydrido, or another substituent as shown in the gure. The other example builds a carbosilane with four backbone silane groups per methylene backbone unit (85). Among the methods attempted for the synthesis of polyferrocene, the reductive coupling of 1,10 -diiodoferrocene with a stoichiometric quantity of magnesium leads to a short polymer (M N 5000) (see Fig. 2.43). Even so, this reductive coupling is as good as any other synthetic method for synthesizing the unsubstituted polyferrocene. Reductive coupling may also be involved in the synthesis of the soluble ruthenium(II) polymers (Fig. 2.5) from ruthenium(III) monomers discussed previously. In the second paper of their synthesis (19) Kelch and Rehahn note the addition of a reducing agent such as ethylmorpholine to ensure complete reduction to ruthenium(II) during the nal stages of the polymerization. No reducing agent was noted in the original communication (20), in which average degrees of polymerization were of the order of 10 or 15; therefore, the reduction must be fairly spontaneous.

Revonsuo, A. (2003). The reinterpretation of dreams. In E.F. Pace-Schott, M. Solms, M. Blagrove, & S. Harnad (Eds.), Sleep and dreaming (pp. 85 109). Cambridge: Cambridge University Press.

associated with the anterior positioning appliance, I do not view it as a potential longterm therapy.

students said that it was wrong to lie to best friends, but they saw nothing wrong in lying if it secured a job. They also thought that employers expected candidates to exaggerate qualities when applying. A MORI poll shed light on the scale of lying in job applications. Twenty- ve percent of Britain s working population had misled their potential employers when applying for a job. Those lies ranged from providing false details of personal skills and qualities to exaggerated experience and salary (King, 2006; see also Birkeland, Manson, Kisamore, Brannick, & Smith, 2006; Levashina & Campion, 2006; Pontari & Schenkler, 2006; and Weiss & Feldman, 2006). Rowatt, Cunningham, and Druen (1998) found that 90% of participants admitted being willing to tell a lie to a prospective date. About 40% of men and women indicated that they actually had told a lie to initiate a date with an attractive member of the opposite sex (Rowatt, Cunningham, & Druen, 1999). Also DePaulo s diary study revealed that people lied relatively often to their romantic partners in the early stages of their relationship (once in every three social interactions). One possible explanation is that people worry whether their true self is lovable enough to attract and keep these partners, and they therefore present themselves as they wish they are instead of how they actually are (e.g., the self-edited perspective, DePaulo & Kashy, 1998).

Figure 15.8. The computer reconstruction obtained from the Lohmann hologram of the gray-level image.

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Here s a muffin the kids can still take to school this recipe doesn t call for nuts! Preparation Time: 12 minutes Cooking Time: 20 minutes with sugar/15 minutes with Splenda Yield: 12 muffins

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